Soret forced Rayleigh scattering instrument for simultaneous detection of two-wavelength signals to measure Soret coefficient and thermodiffusion coefficient in ternary mixtures
نویسندگان
چکیده
منابع مشابه
Advances in Thermodiffusion and Thermophoresis (soret Effect) in Liquid Mixtures
Recent advances in thermodiffusion (Soret effect) in binary and higher multicomponent liquid mixtures are reviewed. The mixtures studied include the hydrocarbon, associating, molten metal and semiconductor, polymer, and DNA mixtures. The emphasis is placed on the theoretical works, particularly models based on the nonequilibrium thermodynamics, although other approaches such as the statistical,...
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Soret coefficients of the ternary system of poly(ethylene oxide) in mixed water/ethanol solvent were measured over a wide solvent composition range by means of thermal diffusion forced Rayleigh scattering. The Soret coefficient S(T) of the polymer was found to change sign as the water content of the solvent increases with the sign change taking place at a water mass fraction of 0.83 at a temper...
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Convection in an inclined layer of fluid is affected by the presence of a component of the acceleration of gravity perpendicular to the density gradient that drives the convective motion. In this work we investigate the solutal convection of a colloidal suspension characterized by a negative Soret coefficient. Convection is induced by heating the suspension from above, and at large solutal Rayl...
متن کاملReverse nonequilibrium molecular dynamics calculation of the Soret coefficient in liquid heptane/benzene mixtures.
We studied the thermal diffusion behavior of mixtures of benzene and heptane isomers by reverse nonequilibrium molecular dynamics. For n-heptane/benzene mixtures, we investigated the concentration dependence of the Soret coefficient. The Soret coefficient for equimolar mixtures of the three heptane isomers 3-methylhexane, 2,3-dimethylpentane, and 2,4-dimethylpentane in benzene has been calculat...
متن کاملSoret Coefficient and Thermoelectric Power of Thermocells Containing Molten Binary Mixtures
For an ionic melt consisting of two components and of three ion constituents, we derive the interrelation between the Soret coefficient and the initial and final values of the thermoelectric power of a thermocell containing the melt considered. We only use the general formulas of Thermodynamics of Irreversible Processes and there is no restriction with respect to the valency types of the electr...
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ژورنال
عنوان ژورنال: Review of Scientific Instruments
سال: 2018
ISSN: 0034-6748,1089-7623
DOI: 10.1063/1.5013292